##plugins.themes.bootstrap3.article.main##

V. Davamani S. Arulmani E. Parameswari T. Thangaselvabai T.N. Balamohan

Abstract

In this work we used flower waste biomass as a biosorbent to remove Cr from tannery effluent through column experiments. The sorption capacities of biosorbent (Fine, coarse and rough grades) were also evaluated by employing chemical pretreatments viz., sodium hydroxide, acetic acid, glutaraldehyde and hydrogen peroxide. The order of percentage removal of Cr using the above pretreatments was: 10% hydrogen peroxide < Raw powdered-FWB < 2% Gluteraldehyde < 10% Acetic acid < 0.1N sodium hydroxide. Among the different grades of biosorbents used, fine grade adsorbed more Cr (70 %) than that of coarse (64%) and rough (62 %) sorbents. The removal percentage of Cr from tannery was analyzed by using Atomic Absorption Spectroscopy, the functional groups which are responsible for adsorption was examined by Fourier Transform- Infrared Spectroscopy and the amorphous behaviour of FWB facilitating metal biosorption was indicated by the X-ray diffractogram. This study showed that pretreated flower waste biomass is a potential sorbent of Cr, which could be successfully used to reduce the Cr content in tannery effluent.

##plugins.themes.bootstrap3.article.details##

##plugins.themes.bootstrap3.article.details##

Keywords

AAS, Chromium, Flower waste biomass, Tannery

References
Bhatti, H.N., Samin, S., Hanif, M.A. (2008). Enhanced Removal of Cu(II) and Pb(II) from Aqueous Solutions by Pretreated Biomass of Fusarium Solani. J. Chinese. Chem. Soc., 55: 1235.
Bux, F., Kasan, H. (1994). Comparison of selected methods for relative assessment of surface charge on waste sludge biomass. Water SA, 20:73-76.
Dantas Neto, A.A., Dantas, T.N.C., Moura, M.C.P.A. (2004). Evaluation and optimization of chromium removal from tannery effluent by microemulsion in the Morris extractor; J. Hazard. Mater., B114-122.
Das, N., Charumathi, D., Vimala, R. (2007). Effect of pretreatment on Cd2+ biosorption by mycelial biomass of Pleurotus florida. Afr. J. Biotechnol., 6: 2555-2558.
Ebrahim, A, M.A.Gautham, N. Jawahar, and S. Hariram. (2011). Preliminary attempt to reduce total dissolved solids in ground water using different plant parts. International Journal of Pharma and Bio Sciences, 2(2): 414-422.
El-Sayed, M. and El-Morsy. (2004). Cunninghamella echinulata, a new biosorbent of metal ions from polluted water in Egypt. Mycologia, 96:1183-1189.
Fourest, E., Roux, J.C. (1992). Heavy Metal Biosorption by Fungal Mycelial by-Products Mechanisms and Influence of pH. Appl. Microbiol. Biotechnol.: 37, 399-403.
Hana, X., Wongb,Y.S. and Nora Fung Y.T. (2006). Surface complexation mechanism and modeling in Cr(III) biosorption by a microalgal isolate, Chlorella miniata. Journal of Colloid and Interface Science, 303 : 365–371.
Hasar, H. (2003). Adsorption of Nickel (II) from aqueous solution on to activated carbon prepared from almond husk. J. Hazard. Mater.: B 97, 49-57.
Huang, C.P., and Huang, C.P. (1996). Application of Aspergillus oryzae and Rhizopus oryzae. Water Research, 30: 1985-1990.
Jayabalakrishnan, R.M. and Mahimaraja, S. (2007). Adsorption of Hexavalent Chromium on to Raw Vermiculite Grades as a Function of Solution Concentration. J. Appl. Sci. Res. 3(11): 1262-1266.
Kapoor, A. and Viraraghavan, T. (1998). Removal of heavy metals from aqueous solution using immobilized fungal biomass in continuous mode. Water Research, 32: 1968-1977.
Mohan, D., K.P. Singh, V.K. Singh. (2006). Trivalent chromium removal from waste water using low cost acivated carbon derived from agricultural waste material and activated carbon fabric cloth. J. Hazard Mater 135: 280-295
Muraleedharan, T.R. and Venkobachar, C. (1990). Mechanism of biosorption of Cu2+ by Ganoderma lucidum. Biotechnology Bioengineering, 35: 320-325.
Onwuka, J. C., Ajibola, V. O., Kagbu, J. A. and Manji A. (2011). Biosorption of Cr(VI) and Co(II) ions from synthetic wastewater using dead biomass of fresh water green algae Cosmarium panamense. J. Arch. Appl. Sci. Res.,.3(6):191-207.
Reya, I., Lakshmi Prabha, M. and Renitta, R,E. (2013). Equilibrium and kinetic studies on biosorption of Cr (VI) using novel Aspergillus jegita isolated from tannery effluent. Res. J. Chem. Environ. 17(4):72-78.
Sag, Y.I., Tata, B. and Kutsal, T. (2003). Biosorption of Pb (II) and Cu (II) by activated sludge in batch and continuous- stirred reactors. Bioresour. Technolol.: 87: 27.
Saleh, M., Al-Garni, Khaled, M. G. and Abdulaziz, S. B. (2009). Biosorption characteristics of Aspergillus fumigatus in removal of cadmium from an aqueous solution. Afr. J. Biotechnol., 8: 4163-4172.
Salim, R., Al-Subbu, M.M.S. and Qasho, A. S. (1994). Removal of Lead from Polluted Water Using Decaying Leaves. J. Environ. Sci. Health. : 29: 2087.
Sumathi, K.M, Mahimairaja, S, Naidu, R. (2005). Use of low -cost biological wastes and vermiculite for removal of chromium from tannery effluent. Bioresour.Technol., 96(3):309-16.
Tobin, JM. and Roux, JC. (1998). Mucor biosorbent for chromium removal from tanning effluent. Water Res. 32:1407–16.
USEPA., 1979. Method 218.1. Atomic absorption direct aspiration. In: Methods for Chemical Analysis of Water and Wastes. EPA- 600/4-7-020 USEPA. Environmental Monitoring and Support Laboratory, Cincinnati, OH.
Vargas, C. Brandao, P.F.B., Agreda, J and Castillo, E. (2012). Bioadsorpion using compost: An alternative for removal of chromium (VI) from aqueous solutions. Bioresources, (3): 2711-2727.
Yan, G. and Viraraghavan, T. (2000). Effect of pretreatment on the bioadsorption of heavy metals on Mucor rouxi. Water SA, 26: 119-123.
Yayuz, H., Denizli, A., Gungunes, H., Safarikova, M. and Safarik, I. (2006). Biosorption of mercury on magnetically modified yeast cells. Separation and Purification Technology 52: 253-260.
Section
Research Articles

How to Cite

Utilization of flower waste for the removal of chromium from tannery effluent. (2016). Journal of Applied and Natural Science, 8(3), 1198-1204. https://doi.org/10.31018/jans.v8i3.940