Experimental investigation of anti-corrosive behaviour of Beta vulgaris: A green approach
Article Main
Abstract
The loss of metals due to corrosion can be prevented using green inhibitors. Using natural and eco-friendly plant products is futuristic, preventing the environment from toxic and harmful chemicals. The present study aimed to investigate whole beetroot (BR, Beta vulgaris) for its anti-corrosion behaviour by galvanostatic polarization and electrochemical impedance techniques at a temperature between 298 K- 328 K. The temperature study would help in proposing BR's adsorption mechanism on metal surfaces. The maximum inhibition efficiency of 94% at 298 K for 5% BR was observed, whereas a minimum of 75% was obtained for 1% BR at 328 K. It was found to be a mixed-type inhibitor that followed Langmuir isotherm. From thermodynamic studies, ΔGoads was found to be -13.64 kJ/mol, which revealed that BR adsorbed physically on the surface of mild steel. Rct values increased while Cdl values decreased on exposure of metal surface with BR extract. The scanning electron micrographs (SEM) and atomic force micrographs (AFM) witnessed the formation of a protective layer on the mild steel surface, which served as a barrier between the metal and corrosive medium. The present study provides a remedy for the financial and structural losses due to metal corrosion in an acidic medium.
Article Details
Article Details
Keywords
Corrosion, Electrochemical Impedance Spectroscopy, Mild Steel, Langmuir isotherm, Physical adsorption
References
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Goyal, M., Kumar, S., Bahadur, I., Verma, C. & Ebenso, E. E. (2018). Organic corrosion inhibitors for industrial cleaning of ferrous and non-ferrous metals in acidic solutions: A review. Journal of Molecular Liquids, 256, 565-573. https://doi.org/10.1016/j.molliq.2018.02.045
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Joycee, S. C., Raja, A. S., Amalraj, A. S. & Rajendran, S. (2022). Corrosion mitigation by an eco-friendly inhibitor: Beta vulgaris (beetroot) extract on mild steel in simulated oil well water medium. Int. J. Corros. Scale Inhib, 11(1), 82-101. https://doi.org/10.17675/2305-6894-2022-11-1-4
Kanojia, R. & Singh, G. (2005). An interesting and efficient organic corrosion inhibitor for mild steel in acidic medium. Surface engineering, 21(3), 180- 186.https://doi.org/10.1179/174329405x49985
Kumar, S. A., Sankar, A., Kumaravel, M., & Rameshkumar, S. (2013). The Inhibition of Mild Steel Corrosion in Sulphuric Acid Media by Acorus Calamus Extract. International Journal of Engineering Innovations and Research, 2(2), 167.
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https://doi.org/10.1016/j.heliyon.2020.e05560
Medupin, R. O., Ukoba, K., Yoro, K. O. & Jen, T. C. (2023). Sustainable approach for corrosion control in mild steel using plant-based inhibitors: A review. Materials Today Sustainability, 100373. https://doi.org/10.1016/j.mtsust.2023.100373
Mobin, M., Basik, M. & El Aoufir, Y. (2019). Corrosion mitigation of mild steel in acidic medium using Lagerstroemia speciosa leaf extract: A combined experimental and theoretical approach. Journal of Molecular Liquids, 286, 110890. https://doi.org/10.1016/j.molliq.2019.110890
Muthamma, K., Kumari, P., Lavanya, M., & Rao, S. A. (2021). Corrosion inhibition of mild steel in acidic media by N- [(3, 4-Dimethoxyphenyl) Methyleneamino]-4-Hydroxy-Benzamide. Journal of Bio-and Tribo-Corrosion, 7, 1-19. https://doi.org/10.1007/s40735-020-00439-7
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Experimental investigation of anti-corrosive behaviour of Beta vulgaris: A green approach. (2023). Journal of Applied and Natural Science, 15(3), 1315-1325. https://doi.org/10.31018/jans.v15i3.4969
