Experimental investigation of anti-corrosive behaviour of Beta vulgaris: A green approach
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Abstract
The loss of metals due to corrosion can be prevented using green inhibitors. Using natural and eco-friendly plant products is futuristic, preventing the environment from toxic and harmful chemicals. The present study aimed to investigate whole beetroot (BR, Beta vulgaris) for its anti-corrosion behaviour by galvanostatic polarization and electrochemical impedance techniques at a temperature between 298 K- 328 K. The temperature study would help in proposing BR's adsorption mechanism on metal surfaces. The maximum inhibition efficiency of 94% at 298 K for 5% BR was observed, whereas a minimum of 75% was obtained for 1% BR at 328 K. It was found to be a mixed-type inhibitor that followed Langmuir isotherm. From thermodynamic studies, ΔGoads was found to be -13.64 kJ/mol, which revealed that BR adsorbed physically on the surface of mild steel. Rct values increased while Cdl values decreased on exposure of metal surface with BR extract. The scanning electron micrographs (SEM) and atomic force micrographs (AFM) witnessed the formation of a protective layer on the mild steel surface, which served as a barrier between the metal and corrosive medium. The present study provides a remedy for the financial and structural losses due to metal corrosion in an acidic medium.
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Keywords
Corrosion, Electrochemical Impedance Spectroscopy, Mild Steel, Langmuir isotherm, Physical adsorption
References
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Badreah A. Al Jahdaly, (2023). Rosmarinus officinalis extract as eco-friendly corrosion inhibitor for copper in 1 M nitric acid solution: Experimental and theoretical studies, Arabian Journal of Chemistry, 16 (1), 104411, ISSN 1878-5352, https://doi.org/10.1016/j.arabjc.2022.104411.
Badr, E. A., Bedair, M. A. & Shaban, S. M. (2018). Adsorption and performance assessment of some imine derivatives as mild steel corrosion inhibitors in 1.0 M HCl solution by chemical, electrochemical and computational methods. Materials Chemistry and Physics, 219, 444-460.https://doi.org/10.1016/j.matchemphys.2 018.08.041
Balázs, S. (1994). Zöldségtermesztők kézikönyve. Mezőgazda Kiadó, Budapest, 631-639.
Bashir, S., Singh, G. & Kumar, A. (2017). Shatavari (Asparagus Racemosus) as green corrosion inhibitor of aluminium in acidic medium. J Mater. Environ. Sci., 8(12), 4284-4291.https://doi.org/10.26872/jmes.2017.8.12.451
Bashir, S., Singh, G., & Kumar, A. (2018). An investigation on mitigation of corrosion of aluminium by Origanum vulgare in acidic medium. Protection of Metals and Physical Chemistry of Surfaces, 54, 148-152. https://doi.org/10.1134/s2070205118010185
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Chen, M. F., Chen, Y., Lim, Z. J. & Wong, M. W. (2022). Adsorption of imidazolium-based ionic liquids on the Fe (1 0 0) surface for corrosion inhibition: Physisorption or chemisorption?. Journal of Molecular Liquids, 367, 120489. https://doi.org/10.1016/j.molliq.2022.120489
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Chugh, B., Singh, A. K., Thakur, S., Pani, B., Lgaz, H., Chung, I. M., ... & Ebenso, E. E. (2020). Comparative investigation of corrosion-mitigating behavior of thiadiazole-derived bis-schiff bases for mild steel in acid medium: experimental, theoretical, and surface study. ACS omega, 5(23), 13503. https://doi.org/10.1021/acsomega.9b04274
Dhaundiyal, P., Bashir, S., Sharma, V. & Kumar, A. (2019). An investigation on mitigation of corrosion of mildsteel by Origanum vulgare in acidic medium. Bulletin of the Chemical Society of Ethiopia, 33(1), 159-168. https://doi.org/10.4314/bcse.v33i1.16
Durowaye, S. I., Durowaye, V. O. & Begusa, B. M. (2014). Corrosion Inhibition of Mild Steel in Acidic Medium by Methyl Red (2, 4-Dimethylamino-2'-carboxylazobenzene). Int. J. Eng. Technol, 4(8), 469-475.
Fu, S., Yang, X., Peng, Y., Wang, Q., Sun, Q., Zhang, J., ... & Li, J. (2023). Corrosion Behaviors of Tetrasodium Iminodisuccinate (IDS) as an Environmentally Friendly Inhibitor: Experimental and Theoretical Studies. Coatings, 13(3), 613. https://doi.org/10.3390/coatings13030613
Gao, X., Zhao, C., Lu, H., Gao, F. & Ma, H. (2014). Influence of phytic acid on the corrosion behavior of iron under acidic and neutral conditions. Electrochimica Acta, 150, 188-196.https://doi.org/10.1016/j.electacta.2014.09.160
Goyal, M., Kumar, S., Bahadur, I., Verma, C. & Ebenso, E. E. (2018). Organic corrosion inhibitors for industrial cleaning of ferrous and non-ferrous metals in acidic solutions: A review. Journal of Molecular Liquids, 256, 565-573. https://doi.org/10.1016/j.molliq.2018.02.045
Habeeb, H. J., Luaibi, H. M., Dakhil, R. M., Kadhum, A. A. H., Al-Amiery, A. A., & Gaaz, T. S. (2018). Development of new corrosion inhibitor tested on mild steel supported by electrochemical study. Results in physics, 8, 1260-1267. https://doi.org/10.1016/j.rinp.2018.02.015
Joycee, S. C., Raja, A. S., Amalraj, A. S. & Rajendran, S. (2022). Corrosion mitigation by an eco-friendly inhibitor: Beta vulgaris (beetroot) extract on mild steel in simulated oil well water medium. Int. J. Corros. Scale Inhib, 11(1), 82-101. https://doi.org/10.17675/2305-6894-2022-11-1-4
Kanojia, R. & Singh, G. (2005). An interesting and efficient organic corrosion inhibitor for mild steel in acidic medium. Surface engineering, 21(3), 180- 186.https://doi.org/10.1179/174329405x49985
Kumar, S. A., Sankar, A., Kumaravel, M., & Rameshkumar, S. (2013). The Inhibition of Mild Steel Corrosion in Sulphuric Acid Media by Acorus Calamus Extract. International Journal of Engineering Innovations and Research, 2(2), 167.
Larabi, L., Harek, Y., Benali, O. & Ghalem, S. (2005). Hydrazide derivatives as corrosion inhibitors for mild steel in 1 M HCl. Progress in Organic Coatings, 54(3), 256-262.https://doi.org/10.1016/j.porgcoat.2005.06.015
Loto, R. T. & Tobilola, O. (2018). Corrosion inhibition properties of the synergistic effect of 4-hydroxy-3-methoxybenzaldehyde and hexadecyltrimethylammoniumbromide on mild steel in dilute acid solutions. Journal of King Saud University-Engineering Sciences, 30(4), 384-390. https://doi.org/10.1016/j.jksues.2016.10.001
Mathew, Z. P., Rajan, K., Augustine, C., Joseph, B. & John, S. (2020). Corrosion inhibition of mild steel using poly (2-ethyl-2-oxazoline) in 0.1 M HCl solution. Heliyon, 6(11), e05560.
https://doi.org/10.1016/j.heliyon.2020.e05560
Medupin, R. O., Ukoba, K., Yoro, K. O. & Jen, T. C. (2023). Sustainable approach for corrosion control in mild steel using plant-based inhibitors: A review. Materials Today Sustainability, 100373. https://doi.org/10.1016/j.mtsust.2023.100373
Mobin, M., Basik, M. & El Aoufir, Y. (2019). Corrosion mitigation of mild steel in acidic medium using Lagerstroemia speciosa leaf extract: A combined experimental and theoretical approach. Journal of Molecular Liquids, 286, 110890. https://doi.org/10.1016/j.molliq.2019.110890
Muthamma, K., Kumari, P., Lavanya, M., & Rao, S. A. (2021). Corrosion inhibition of mild steel in acidic media by N- [(3, 4-Dimethoxyphenyl) Methyleneamino]-4-Hydroxy-Benzamide. Journal of Bio-and Tribo-Corrosion, 7, 1-19. https://doi.org/10.1007/s40735-020-00439-7
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Experimental investigation of anti-corrosive behaviour of Beta vulgaris: A green approach. (2023). Journal of Applied and Natural Science, 15(3), 1315-1325. https://doi.org/10.31018/jans.v15i3.4969
