Sorption of Arsenic(III) from wastewater using Prosopis spicigera L. wood (PsLw) carbon-polyaniline composite
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Abstract
Water contamination by toxic heavy metal ions causes a serious public health problem for humans. The present work reports the development of a new adsorbent of PsLw carbon-polyaniline composite by direct oxidation polymerisation of aniline with PsLw carbon for the removal of arsenic (As). The structure and morphologies of the adsorbent were characterised by Fourier transform infrared spectroscopy (FTIR) and Scanning electron microscopy (SEM). The ability of the adsorbent for the removal of As(III) was estimated by batch and kinetic studies. The optimum adsorption behaviour of the adsorbent was measured at pH=6.0. The equilibrium process was found to be in good agreement with Langmuir adsorption isotherm and the maximum adsorption capacity was 98.8 mg/g for an initial concentration of 60 mg/L at 30 °C. The kinetic study followed pseudo-second-order kinetics. Thermodynamic parameters predict the spontaneous, feasible and exothermic nature of adsorption. Column operation was carried out to remove As(III) bulk and column data obeys the Thomas model. The results indicated that PsLw carbon-polyaniline composite can be employed as an efficient adsorbent than polyaniline for removal of As(III) from wastewater.
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Keywords
Adsorption, Isotherm, Mass transfer, Polyaniline, PsLw carbon, Thomas model
References
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Ansari, R., Feizy, J. & Delavar, A.F. (2008). Removal of Arsenic ions from aqueous solutions using conducting polymers. E. J. Chem., 5(4), 853-863.
Bhaumik, M., Noubactep, C., Gupta, V.K., McCrindle, R.I. & Maity, A. (2015). Polyaniline/Feo composite nanofibers: An excellent adsorbent for the removal of arsenic from aqueous solution. Chem. Eng. J., 271, 135–146.
Boeva, Z.A., & Sergeyev, V.G. (2014). Polyaniline: synthesis, properties, and application, Polym. Sci. Ser C., 56, 144–153.
Chang, Q., Lin, W. & Ying, W.C. (2010). Preparation of iron-impregnated granular activated carbon for arsenic removal from drinking water. J. Hazard. Mater., 184(1-3), 515-522.
Davodi, B. & Jahangiri, M. (2014). Determination of optimum conditions for removal of As (III) and As (V) by polyaniline/polystyrene nanocomposite. Synth. Met., 194, 97-101.
Dutta, S., Manna, K., Srivastava, S.K., Gupta, A.K. & Yadav, M.K. (2020). Hollow polyaniline microsphere/Fe3O4 nanocomposite as an effective adsorbent for removal of arsenic from water. Sci Rep., https://doi.o rg/10.1038/s41598-020-61763-z
Fayazi, M., Ali, M. & Afzali Detal. (2016). Synthesis and application of novel ion-imprinted polymer coated magnetic multi-walled carbon nanotubes for selective solid phase extraction of lead (II) ions. Mater. Sci. Eng C., 60, 365–373.
Ho, Y.S. & McKay, G. (1999). Pseudo-Second Order Model for Sorption Processes. Proc. Biochem., 34, 451-465.
JansiRani, M., Murugan, M., Subramaniam, P. & Subramanian, E. (2014). Adsorptive removal of arsenic from aqueous solution on PSLW carbon (Prosopis spicigera L. wood): Equilibrium, kinetics, thermodynamics and homewater treatment studies. Res. J. Chem. Environ., 18(2), 16.
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Jiang, Y., Liu, Z., Zeng, G., Liu, Y., Shao, B., Li, Z., Liu, Y., Zhang, W. & He, Q. (2018). Polyaniline-based adsorbents for removal of hexavalent chromium from aqueous solution: a mini review. Environ Sci Pollut Res., 25, 6158–6174. https://doi.org/10.1007/s11356-0171188-3
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Mahmoud, M.E., Saad, E.A. & El-Khatib, A.M. (2018). Green solid synthesis of polyaniline-silver oxide nanocomposite for the adsorptive removal of ionic divalent species of Zn/Co and their radioactive isotopes65Zn/60Co. Environ Sci Pollut Res., 25, 22120- 22135. https:// doi.org/1 0.1007/s11356-018-2284-8
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Munoz, J.A., Gonzalo, A. & Valiente, M. (2002). Arsenic adsorption by Fe(III)-loaded open- celled cellulose sponge. Thermodynamic and selectivity aspects. Environ. Sci. Technol., 36, 3405-3411.
Ogata, F., Kawasaki, N., Nakamura, T. & Tanada, S. (2006). Removal of arsenious ion by calcined aluminium oxyhydroxide (boehmite). J. Colloid Interface Sci., 300, 88-93.
Palit, D. & Moulik, S.P. (2000). Adsorption of methylene blue on cellulose from its own solution and its mixture with methyl orange. Indian J. Chem., 39 A, 611-617.
Podder, M.S. & Majumder, C.B. (2016). Kinetic, mechanistic and thermodynamic studies of removal of arsenic using Bacillus arsenicus MTCC 4380 immobilized on surface of granular activated carbon/MnFe2O4 composite. Groundw. Sustain. Dev., 2, 53-72.
Potgiefer, J.H. (1991). Adsorption of methylene blue on activated carbon: An experiment illustrating both the Langmuir and Freundlich isotherms. J. Chem. Edu., 68, 349.
Purwajanti, S. (2016). Mesoporous magnesium oxide hollow spheres as superior arsenite adsorbent: Synthesis and Adsorption Behavior. ACS Appl. Mater. Interfaces. 8, 25306–25312.
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Schwarz, J.A., Driscoll, C.T. & Bharot, A.K. (1984). The zero point of charge of silica-alumina oxide suspensions. J. Colloid Interface Sci., 97, 55-61.
Semerjian, L. (2010). Equilibrium and kinetics of cadmium adsorption from aqueous solutions using untreated Pinushalepensis sawdust. J. Hazard. Mater., 173, 236-242.
Shabnam, R. (2017). Novel magnetically doped Epoxide functional cross-linked hydrophobic Poly(lauryl methacrylate) composite polymer particles for removal of As(III) from aqueous solution. Ind. Eng. Chem. Res., 56, 7747–7756.
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Weber, T.W. & Chakraborti, R.K. (1974). Pore and solid diffusion models for fixed-bed adsorbers. J. Am. Inst. Chem. Eng., 20, 228-238.
Yang, P.C., Du, J., Peng, Q., Qiao, R., Chen, W., Xu, C., Shuai, Z. & Gao, M. (2009). Polyaniline/Fe3O4 nanoparticle composite: Synthesis and reaction mechanism. J. Phys. Chem. B, 113, 5052–5058.
Zhou, Q., Wang, J., Liao, X., Xiao, J. & Fan, H. (2015). Removal of As(III) and As(V) from water using magnetic core-shell nanomaterial Fe3O4@ polyaniline. Int. J. Green Technol., 1, 54–64.
Zhu, H., Jia, Y., Wu, X. & Wang, H. (2009). Removal of arsenic from water by supported nano zero-valent iron on activated carbon. J. Hazard. Mater., 172, 1591–1596.
Agrawal, S. & Singh, N.B. (2016). Removal of arsenic from aqueous solution by an adsorbent nickel ferrite-polyaniline nanocomposite. Indian J. Chem. Technol., 23, 374-383.
Ansari, R., Feizy, J. & Delavar, A.F. (2008). Removal of Arsenic ions from aqueous solutions using conducting polymers. E. J. Chem., 5(4), 853-863.
Bhaumik, M., Noubactep, C., Gupta, V.K., McCrindle, R.I. & Maity, A. (2015). Polyaniline/Feo composite nanofibers: An excellent adsorbent for the removal of arsenic from aqueous solution. Chem. Eng. J., 271, 135–146.
Boeva, Z.A., & Sergeyev, V.G. (2014). Polyaniline: synthesis, properties, and application, Polym. Sci. Ser C., 56, 144–153.
Chang, Q., Lin, W. & Ying, W.C. (2010). Preparation of iron-impregnated granular activated carbon for arsenic removal from drinking water. J. Hazard. Mater., 184(1-3), 515-522.
Davodi, B. & Jahangiri, M. (2014). Determination of optimum conditions for removal of As (III) and As (V) by polyaniline/polystyrene nanocomposite. Synth. Met., 194, 97-101.
Dutta, S., Manna, K., Srivastava, S.K., Gupta, A.K. & Yadav, M.K. (2020). Hollow polyaniline microsphere/Fe3O4 nanocomposite as an effective adsorbent for removal of arsenic from water. Sci Rep., https://doi.o rg/10.1038/s41598-020-61763-z
Fayazi, M., Ali, M. & Afzali Detal. (2016). Synthesis and application of novel ion-imprinted polymer coated magnetic multi-walled carbon nanotubes for selective solid phase extraction of lead (II) ions. Mater. Sci. Eng C., 60, 365–373.
Ho, Y.S. & McKay, G. (1999). Pseudo-Second Order Model for Sorption Processes. Proc. Biochem., 34, 451-465.
JansiRani, M., Murugan, M., Subramaniam, P. & Subramanian, E. (2014). Adsorptive removal of arsenic from aqueous solution on PSLW carbon (Prosopis spicigera L. wood): Equilibrium, kinetics, thermodynamics and homewater treatment studies. Res. J. Chem. Environ., 18(2), 16.
Jeffery, G.H., Bassett, J., Mendham, J. & Denny, R.C. (1989). Vogel’s Textbook of Quantitative Chemical Analysis (5th edition). Longmann Scientific & Technical, England.
Jiang, Y., Liu, Z., Zeng, G., Liu, Y., Shao, B., Li, Z., Liu, Y., Zhang, W. & He, Q. (2018). Polyaniline-based adsorbents for removal of hexavalent chromium from aqueous solution: a mini review. Environ Sci Pollut Res., 25, 6158–6174. https://doi.org/10.1007/s11356-0171188-3
Lagergren, S. (1898). Zurtheorie der sogenannten adsorption geloesterstoffe, Kungligasvenska Ventenskapsakademiens. Handlingar, 24, 1–39.
Lashkenari, M.S., Davodi, B. & Eisazadeh, H. (2011). Removal of arsenic from aqueous solution using polyaniline/rice husk nanocomposite. Korean. J. Chem. Eng., 28, 1532–1538.
Li, J., Huang, Y. & Shao, D. (2015). Conjugated polymer-based composites for water purification. In: Saini P (ed) Fundamentals of conjugated polymer blends, copolymers and composites: synthesis, properties, and applications. Scrivener, 581-620.
Mahmoud, M.E., Saad, E.A. & El-Khatib, A.M. (2018). Green solid synthesis of polyaniline-silver oxide nanocomposite for the adsorptive removal of ionic divalent species of Zn/Co and their radioactive isotopes65Zn/60Co. Environ Sci Pollut Res., 25, 22120- 22135. https:// doi.org/1 0.1007/s11356-018-2284-8
Mckay, G., Balir, H.S. & Garden, J.R. (1982). Adsorption of dyes on Chitin I equilibrium studies. J. Appl. Polym Sci., 27, 3043-3057.
Nodeh, M.K.M., Gabris, M.A., Nodeh, H.R. & Bidhendi, M.E (2018). Efficient removal of arsenic(III) from aqueous media using magnetic polyaniline-doped strontium–titanium nanocomposite. Environ Sci Pollut Res., 25, 16864-16874.https://doi.org/ 10.1007/ s11356-018-1870-0
Mohan, D., Pittman, C.U. (2007). Arsenic removal from water/wastewater using adsorbents-a critical review. J Hazard Mater., 142, 1–53.
Munoz, J.A., Gonzalo, A. & Valiente, M. (2002). Arsenic adsorption by Fe(III)-loaded open- celled cellulose sponge. Thermodynamic and selectivity aspects. Environ. Sci. Technol., 36, 3405-3411.
Ogata, F., Kawasaki, N., Nakamura, T. & Tanada, S. (2006). Removal of arsenious ion by calcined aluminium oxyhydroxide (boehmite). J. Colloid Interface Sci., 300, 88-93.
Palit, D. & Moulik, S.P. (2000). Adsorption of methylene blue on cellulose from its own solution and its mixture with methyl orange. Indian J. Chem., 39 A, 611-617.
Podder, M.S. & Majumder, C.B. (2016). Kinetic, mechanistic and thermodynamic studies of removal of arsenic using Bacillus arsenicus MTCC 4380 immobilized on surface of granular activated carbon/MnFe2O4 composite. Groundw. Sustain. Dev., 2, 53-72.
Potgiefer, J.H. (1991). Adsorption of methylene blue on activated carbon: An experiment illustrating both the Langmuir and Freundlich isotherms. J. Chem. Edu., 68, 349.
Purwajanti, S. (2016). Mesoporous magnesium oxide hollow spheres as superior arsenite adsorbent: Synthesis and Adsorption Behavior. ACS Appl. Mater. Interfaces. 8, 25306–25312.
Reynolds, T.D. & Richards, P.A. (1996). Unit operations and process in Environmental Engineering. PWS Boston, USA.
Roy, P., Mondal, N.K., Bhattacharya, S., Das, B. & Das, K. (2013). Removal of arsenic(III) and arsenic(V) on chemically modified low-cost adsorbent: batch and column operations. Appl. Water Sci., 3, 293- 309.
Schwarz, J.A., Driscoll, C.T. & Bharot, A.K. (1984). The zero point of charge of silica-alumina oxide suspensions. J. Colloid Interface Sci., 97, 55-61.
Semerjian, L. (2010). Equilibrium and kinetics of cadmium adsorption from aqueous solutions using untreated Pinushalepensis sawdust. J. Hazard. Mater., 173, 236-242.
Shabnam, R. (2017). Novel magnetically doped Epoxide functional cross-linked hydrophobic Poly(lauryl methacrylate) composite polymer particles for removal of As(III) from aqueous solution. Ind. Eng. Chem. Res., 56, 7747–7756.
Thomas, H.C. (1948). Chromatography: a problem in kinetics. Ann. N.Y. Acad Sci., 49, 161-182.
Weber, T.W. & Chakraborti, R.K. (1974). Pore and solid diffusion models for fixed-bed adsorbers. J. Am. Inst. Chem. Eng., 20, 228-238.
Yang, P.C., Du, J., Peng, Q., Qiao, R., Chen, W., Xu, C., Shuai, Z. & Gao, M. (2009). Polyaniline/Fe3O4 nanoparticle composite: Synthesis and reaction mechanism. J. Phys. Chem. B, 113, 5052–5058.
Zhou, Q., Wang, J., Liao, X., Xiao, J. & Fan, H. (2015). Removal of As(III) and As(V) from water using magnetic core-shell nanomaterial Fe3O4@ polyaniline. Int. J. Green Technol., 1, 54–64.
Zhu, H., Jia, Y., Wu, X. & Wang, H. (2009). Removal of arsenic from water by supported nano zero-valent iron on activated carbon. J. Hazard. Mater., 172, 1591–1596.
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How to Cite
Sorption of Arsenic(III) from wastewater using Prosopis spicigera L. wood (PsLw) carbon-polyaniline composite. (2021). Journal of Applied and Natural Science, 13(4), 1283-1293. https://doi.org/10.31018/jans.v13i4.2969
