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A. K. Chopra Arun Kumar Sharma

Abstract

The present investigation observed the effect of operating time, current density, pH and supporting electrolyte on the removal efficiency of Turbidity (TD) and Biochemical oxygen demand (BOD) of secondarily treated sewage (STS) using electrochemical process. A glass chamber of 2 litre volume was used for the experiment with two electrode plates of aluminum, each having an area of 125 cm2 and 2 cm distance apart from each other. The treatment showed that the removal efficiency of TD and BOD increased to 87.41 and 81.38 % respectively with the
increase of current density (1.82 -7.52 mA/cm2), time (5 - 40 mins.) and different pH (4-8) of the STS. The most effective removal efficiency was observed around the pH 7. Further, 0.5 g/l NaCl as a supporting electrolyte for electrochemical treatment of STS was found to be more efficient for an increase to 95.56 % and 86.99 % for the removal of TD and BOD at 7.52 mA/cm2 current density in 40 mins. respectively. The electrode and energy consumption was found to vary from 2.52 x10-2 to 10.51 x10-2 kg Al/m3 and 2.76 kwh/m3 to 45.12 kWh/m3 depending on the operating conditions.The kinetic study results revealed that reaction rate (k) increased from 0.0174 to 0.03 min-1 for TD and 0.0169 to 0.024 min-1 for BOD with increase in current density from 1.82 to 7.52 mA/cm2.

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Keywords

Aluminium electrode, BOD, Current density, Electrochemical treatment, Supporting electrolyte

References
Alinsafi, A., Khemis, M., Pons, M.N., Leclerc, J.P., Yaacoubi, A. Benhammou, A. and Nejmeddine, A. (2005). Electrocoagulation of reactive textile dyes and textile wastewater, Chem. Eng. Process., 44: 461–470.
APHA (2005). Standard methods for the examination of water and wastewater (21 st Edn). Washington, D.C.: American Public Health Association.
Ashtoukhy, El., and Amin, N.K. (2010) Removal of acid green dye 50 from wastewater by anodic oxidation and electrocoagulation - A comparative study. Journal of Hazardous Materials, 179: 113–119.
Bayramoglu, M., Kobya, M., Can, O.T. and Sozbir, M., (2004) Operating cost analysis of electrocoagulation of textile dye wastewater. Sep. Purif. Technol., 37: 117–125.
Bensadok, K., Benammar, S., Lapicque, F., and Nezzal, G (2008). Electrocoagulation of cutting oil emulsions using aluminum plate electrodes. J. Hazard. Mater., 152 (1): 423-430.
Bukhari, A. A. (2008). Investigation of the electro-coagulation treatment process for the removal of total suspended solids and turbidity from municipal wastewater. Bioresource Technology, 99: 914-21.
Chen, G. (2004). Electrochemical technologies in wastewater treatment. Separation Purification Technology, 38 : 11–41.
Cho, J.H., Lee, J.E. and Ra, C.S. (2010) Effects of electric voltage and sodium chloride level on electrolysis of swine Wastewater. Journal of Hazardous Materials, 180: 535–541.
Chopra, A. K., Sharma, A. K. and Kumar, V. (2011). Overview of electrolytic treatment: An alternative technology for purification of wastewater. Archives of Applied Science Research, 3(5): 191- 206.
Daneshvar, N., Oladegaragoze, A. and Djafarzadeh, N. (2006) Decolorization of basic dye solutions by electrocoagulation: an investigation of the effect of operational parameters. J. Hazard. Mater., 129 : 116–122.
Eriksson, E., Auûarth. K., Henze. M. and Ledin. A. (2002) Characteristics of grey wastewater. Urban Water, 4: 85–104
Feng, C., Sugiura, N., Shimada, S. and Maekawa, T. (2003) Development of a high performance electrochemical wastewater treatment system. J. Hazard. Mater., 103(1-2): 65–78.
Ghosh D., Medhi C.R., Solanki, H. and Purkait, M.K. (2008) Decolorization of crystal violet solution by electrocoagulation. Journal of Environmental Protection Science, 2: 25 – 35.
Gijzen, H.(2002). Anaerobic digestion for sustainable development: a natural approach. Water Science and Technology, 45: 321-28.
Kobya, M., Demirbas, E., Can, O.T. and Bayramoglu, M. (2006). Treatment of levafix orange textile dye solution by electrocoagulation. J. Hazard. Mater. 132: 183-188.
Lee, W.J. and Pyun, S.I. (1999). Effects of hydroxide ion addition on anodic dissolution of pure aluminum in chloride ion-containing solution. Electrochim. Acta. 44: 4041–4049.
Lung Chou, Wei (2010). Removal and adsorption characteristics of polyvinyl alcohol from aqueous solutions using electrocoagulation. Journal of Hazardous Materials, 177: 842–850.
Mollah, M.Y.A., Schennach, R., Parga, J.R., Cocke, D.L., (2001) Electrocoagulation (EC)- Science and applications. J. Hazard. Mater., B 84: 29–41.
Nasrullah, M., Singh, L. and Wahid, Z. A. (2012) Treatment of Sewage by Electrocoagulation and the Effect of High Current Density. Energy and Environmental Engineering Journal, 1(1): 27-31.
Jolivet, J.P., Solution, D., loxyde. (1994) Condensation des cations en solution aqueuse, chimie des surfaces des oxydes, Inter ´ Edition, Paris, France, (in French).
Philippe R., Haenni, W. and Pupunat, L. (2003) Water treatment without chemistry. Chimia, 57(10):655-78.
Rahmani, A.R. (2008) Removal of water turbidity by the electrocoagulation method. J. Res. Health Sci., 8(1) : 18-24
Szpyrkowicz, L. (2002) Electrocoagulation oftextile wastewater bearing dispersedyes. J. of Ann Chim., 92(10):1025-34.
Tezcan, U., Ugur, U., Koparal S., Bakýr A.S. and Ogutveren, U.(2006). Electrocoagulation of olive mill wastewaters. Separ. Purif. Technol., 52 (1):136-141.
Vlyssides, A.G. and Israilides, C.J. (1997). Detoxification of tannery waste liquors with an electrolysis system. Environ. Pollut. 97: 147-152.
Yetilmezsoy, K., Ilhan, F., Zengin, Z. S., Sakar, S. and Gonullu, M. T. (2009). Decolorization and COD reduction of UASB pretreated poultry manure wastewater by electrocoagulation process: A post-treatment study. Journal of Hazardous Materials, 162: 120–132.
Section
Research Articles

How to Cite

Efficiency of turbidity and BOD removal from secondarily treated sewage by electrochemical treatment. (2012). Journal of Applied and Natural Science, 4(2), 304-309. https://doi.org/10.31018/jans.v4i2.269